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Thom, René
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  Biography http://www-groups.dcs.st-and.ac.uk/~history/Mathematicians/Thom.html
Biography of René Thom.
  Catastrophe Theory http://www.exploratorium.edu/complexity/CompLexicon/catastrophe.html
Rene Thom and Catastrophe Theory.
  Phase Transition http://www.xs4all.nl/~deboot/balanspapers/jansen&maastransition.pdf
The edge of chaos seems to be the phase transition state of the system or the place where choices are made and take place.

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